Unveiling the Powers of Semiconductor Materials

Andrea Galliani
4 min readJul 9, 2023

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In our previous adventures, we explored the captivating world of microelectronics, where tiny electronic components brought devices to life. We encountered characters like transistors, resistors, and capacitors, witnessing their magical abilities. If you want to start from the beginning and follow the path of this journey, here is the list I prepared for you with all the chapters in the correct order: Microelectronics for Uninitiated.

Now, we continue our journey by delving into the extraordinary realm of semiconductor materials and their remarkable properties. So, hold on tight as we unravel the secrets of the microelectronics wonderland!

A silicon crush: the e raw material is polysilicon, which is refined from quartz sand by removing 99.999999999% of other elements present. [1]
A silicon crush: the e raw material is polysilicon, which is refined from quartz sand by removing 99.999999999% of other elements present. [1]

Welcome back, young adventurers! In our microelectronics tales, we discovered the heroes of modern electronics: silicon (Si), germanium (Ge), and gallium arsenide (GaAs). But why are they called semiconductors? These materials possess incredible electrical properties that allow them to control and manipulate electricity, acting as a bridge between conductors and insulators.

Imagine semiconductors as mighty warriors with special powers. Let’s explore their abilities and understand their behavior:

1. Band Gap: Semiconductors have a unique energy barrier called the “band gap.” It separates two worlds — the valence band and the conduction band. The valence band holds electrons tightly, while the conduction band sets them free to move. The size of the band gap determines if a material conducts, insulates, or semiconducts. Semiconductors have a moderate gap, allowing them to conduct electricity under specific conditions.

When a small amount of energy, such as heat or light, is supplied to a semiconductor, it excites electrons from the valence band to the conduction band. This creates charge carriers, enabling the flow of electrical current. By controlling the energy supplied to the semiconductor, we can regulate its conductivity and manipulate the flow of electrons.

A band gap diagram showing the different sizes of band gaps for conductors, semiconductors, and insulators [2]
A band gap diagram showing the different sizes of band gaps for conductors, semiconductors, and insulators [2]

2. Doping: Through “doping,” we can transform these warriors. Adding impurities to their crystal structure changes their properties. N-type doping introduces extra electrons, creating regions with a net negative charge. P-type doping creates electron “holes,” like positive carriers. By combining N-type and P-type regions, we unlock the power to create incredible electronic components.

The doping process alters the concentration of charge carriers within the semiconductor. This allows us to control the conductivity and tailor the semiconductor’s behavior for specific applications. By strategically placing N-type and P-type regions together, we form junctions that give rise to diodes, transistors, and other essential electronic devices.

3. Carrier Mobility: Semiconductors have “carrier mobility,” their super speed! It determines how fast charge carriers (electrons or holes) move when an electric field is applied. High carrier mobility enables faster signal transmission and reduces power consumption.

The crystal structure of semiconductors influences carrier mobility. In some semiconductors, such as silicon, the atomic arrangement provides a relatively open pathway for charge carriers to move. This results in higher carrier mobility, allowing for efficient and speedy electrical communication within the semiconductor material.

4. Temperature Sensitivity: Semiconductor conductivity is affected by temperature. When things heat up, thermal energy excites electrons, increasing their mobility. This temperature dependence affects our warriors’ performance and must be understood and managed carefully.

As temperature rises, more electrons are energized, leading to increased carrier mobility and higher conductivity. However, excessive heat can also cause undesired effects, such as thermal noise and increased power consumption. Therefore, maintaining optimal operating temperatures is crucial for reliable and efficient semiconductor operation.

These extraordinary semiconductor materials serve as the building blocks for electronic devices and integrated circuits. They grant us the power to control and manipulate electrical currents, bringing modern technology to life. From transistors and diodes to microprocessors and memory chips, semiconductors shape the wonders of our world.

But our adventure continues! In the next chapter, we embark on a thrilling journey into microfabrication techniques. We unveil the secrets of how these tiny wonders are brought to life with precision and care. So, gather your courage, dear readers, and join us in the captivating world of microfabrication!

Remember, the realm of microelectronics is full of discoveries waiting to be made. Let your imagination soar as we uncover the mysteries of this magical domain together!

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Andrea Galliani

PhD student in Engineering and Applied Science. I work at the design of front-end circuits for next generation High Energy Physics pixel detectors.