Cedryl Methyl Ether

Chemical Bull
4 min readJan 1, 2024

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Cedryl methyl ether is a synthetic compound that is widely used in the fragrance industry. It is derived from cedrol, a natural sesquiterpene alcohol found in cedarwood oil. Cedryl methyl ether has a woody, ambery, and slightly floral aroma that can enhance the richness and depth of various perfumes. It is also known as cedramber, and it is a low-cost alternative to the more expensive synthetic ambergris forms1.

In this blog, I will explore the history, properties, and applications of cedryl methyl ether, as well as some of the benefits and challenges of using it in fragrance formulations.

History of Cedryl Methyl Ether

Cedryl methyl ether was first synthesized in 1906 by the German chemist Otto Wallach, who is considered the father of modern terpene chemistry. He obtained cedryl methyl ether by reacting cedrol with methyl iodide, and he named it “cedryl methyl ether” after its parent compound. Wallach also discovered many other terpenes and their derivatives, and he was awarded the Nobel Prize in Chemistry in 1910 for his contributions to the field.

Cedryl methyl ether was initially used as a substitute for natural ambergris, a rare and costly substance produced by sperm whales. Ambergris has a complex and unique scent that is highly valued in perfumery, but it is also controversial due to ethical and environmental concerns. Cedryl methyl ether mimics some of the characteristics of ambergris, such as its warm, sweet, and animalic notes, but it is more stable, consistent, and affordable.

Cedryl methyl ether became popular in the 1950s and 1960s, when it was used in several iconic fragrances, such as Chanel №5, Miss Dior, and Shalimar. It was also a key ingredient in the creation of the “chypre” family of perfumes, which are characterized by a contrast between fresh citrus top notes and a woody, mossy base. Cedryl methyl ether added a touch of elegance and sophistication to these compositions, and it is still widely used in modern chypres, such as Guerlain Mitsouko, Estée Lauder Knowing, and Tom Ford Noir de Noir.

Properties and Applications of Cedryl Methyl Ether

Cedryl methyl ether is a colorless to pale yellow liquid with a molecular formula of C16H28O and a molecular weight of 236.39 g/mol. It has a boiling point of 259 °C and a density of 0.976 g/mL at 25 °C. It is soluble in alcohol and most organic solvents, but insoluble in water. It has a refractive index of 1.496 at 20 °C2.

Cedryl methyl ether is mainly used as a fragrance ingredient in perfumes, cosmetics, and personal care products. It can impart a woody, ambery, and slightly floral note to various types of fragrances, such as oriental, floral, woody, and chypre. It can also act as a fixative and a diffuser, meaning that it can enhance the longevity and the projection of a fragrance. It is compatible with many other fragrance materials, such as musks, vanillin, patchouli, sandalwood, and rose.

Cedryl methyl ether is generally considered safe and non-toxic, and it is approved by the International Fragrance Association (IFRA) for use in fragrances. However, some people may be allergic or sensitive to cedryl methyl ether, and it may cause skin irritation or contact dermatitis in some cases. Therefore, it is advisable to perform a patch test before using any product containing cedryl methyl ether, and to follow the recommended usage levels and safety guidelines.

Benefits and Challenges of Using Cedryl Methyl Ether

Cedryl methyl ether has many benefits for the fragrance industry, such as:

  • It is a versatile and adaptable fragrance material that can be used in various types of perfumes, from classic to modern, and from feminine to masculine.
  • It is a cost-effective and sustainable alternative to natural ambergris, which is rare, expensive, and controversial.
  • It is a stable and consistent compound that does not vary in quality or availability, unlike natural materials that may be affected by environmental factors or harvest conditions.
  • It is a powerful and effective compound that can improve the performance and the quality of a fragrance, by adding richness, depth, and complexity.

However, cedryl methyl ether also faces some challenges, such as:

  • It is a synthetic compound that may not appeal to some consumers who prefer natural or organic products, or who are concerned about the environmental impact of synthetic chemicals.
  • It is a common and widely used compound that may lack originality or uniqueness, and that may create a sense of familiarity or boredom among some consumers who are looking for novelty or innovation.
  • It is a potent and dominant compound that may overpower or mask other fragrance notes, and that may require careful blending and balancing to avoid creating a monotonous or overwhelming scent.

Conclusion

Cedryl methyl ether is a synthetic compound that has a long and rich history in the fragrance industry. It is a woody, ambery, and slightly floral aroma that can enhance the richness and depth of various perfumes. It is also a low-cost alternative to the more costly synthetic ambergris forms. It has many benefits, such as its versatility, adaptability, stability, consistency, power, and effectiveness. However, it also faces some challenges, such as its synthetic nature, its commonness, its potency, and its dominance. Therefore, it is important to use cedryl methyl ether wisely and creatively, and to appreciate its value and potential in fragrance formulations.

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