Heike Kamerlingh Onnes: Pioneering Contributions to Low-Temperature Physics and the Discovery of Superconductivity

Gabriel Borges Macedo
9 min readAug 17, 2023

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https://www.espacotempo.com.br/o-que-e-supercondutividade/

Heike Kamerlingh Onnes, born on September 21, 1853, in Groningen, Netherlands, left an indelible mark on the field of physics through his pioneering contributions to low-temperature physics and his groundbreaking discovery of superconductivity. Educated at the University of Groningen and later at the University of Heidelberg under the guidance of eminent scientists like Robert Bunsen and Gustav Kirchhoff, Onnes’ journey in the realm of physics took shape.

Upon obtaining his master’s degree in 1878 and his subsequent doctorate in 1879, with a thesis focusing on the Foucault pendulum, Onnes embarked on a path that would lead him to become a professor of experimental physics at Leiden University. It was during this tenure that he established the renowned Kamerlingh Onnes Laboratory, a hub of innovative research.

One of Onnes’ most notable achievements came in 1908 when he succeeded in liquefying helium for the first time. By skillfully implementing a pre-cooling cycle, he reached temperatures hovering close to absolute zero, a remarkable achievement in itself. However, his groundbreaking moment arrived in 1911 when he uncovered the phenomenon of superconductivity. This was demonstrated when he observed the complete disappearance of electrical resistance in mercury at temperatures nearing absolute zero.

Such transformative discoveries and pioneering work earned Onnes the prestigious Nobel Prize in Physics in 1913. The Nobel committee recognized his efforts in investigating the properties of matter at incredibly low temperatures, which paved the way for innovations like the production of liquid helium. Onnes’ impact extended beyond his scientific accomplishments; he was instrumental in fostering unity among researchers from both Allied and Central Powers following World War I.

Heike Kamerlingh Onnes’ remarkable journey concluded on February 21, 1926, in Leiden, Netherlands. His legacy endures, with his insights into low-temperature physics and superconductivity remaining foundational to our understanding of the fundamental nature of matter.

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Abstract:

Heike Kamerlingh Onnes, a renowned Dutch physicist, left an indelible mark on the field of low-temperature physics with his groundbreaking experiments that led to the liquefaction of helium and the discovery of superconductivity. This scientific article delves into the life and work of this genius, detailing his innovative experiments and the transformative impact they had on our understanding of matter at extremely low temperatures.

Introduction

Born in Groningen, Netherlands, in 1853, Heike Kamerlingh Onnes embarked on a scientific journey that would revolutionize our understanding of the properties of matter at low temperatures. His pioneering work not only marked the first successful liquefaction of helium but also introduced the world to the enigmatic phenomenon of superconductivity.

Liquefaction of Helium

In 1908, Kamerlingh Onnes set out to tackle one of the most challenging frontiers in physics — liquefying helium. At that time, helium remained a stubbornly elusive element to liquefy due to its exceptionally low boiling point of -269 °C. Kamerlingh Onnes approached the challenge with remarkable creativity and dedication.

Employing a multi-stage pre-cooling process and utilizing the Hampson-Linde cycle based on the Joule-Thomson effect, Kamerlingh Onnes managed to lower the temperature to the point of helium’s liquefaction. The experiment involved successive cooling stages, carefully controlling pressure and temperature, and employing cutting-edge apparatus. His breakthrough achievement allowed him to obtain liquid helium and achieve temperatures close to absolute zero. This historic accomplishment not only demonstrated Kamerlingh Onnes’ ingenious experimental techniques but also established a foundation for further research in cryogenics.

Discovery of Superconductivity

Kamerlingh Onnes’ scientific exploration did not stop with helium liquefaction. In 1911, he made another monumental discovery — superconductivity. His research in this area led to the understanding of an extraordinary phenomenon: the complete disappearance of electrical resistance in certain materials at very low temperatures.

The pivotal experiment involved observing the electrical behavior of solid mercury at cryogenic temperatures. Kamerlingh Onnes observed that, at temperatures just above absolute zero, the electrical resistance of mercury vanished completely. This phenomenon was revolutionary and contrary to conventional understanding at the time. It marked the birth of superconductivity — a state in which electric current flows without encountering any resistance.

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Superconductors operate on the principles of quantum mechanics, wherein certain particles form pairs that enable remarkable conduction properties. The particle framework classifies the constituents of the Universe into fermions and bosons. Fermions, like electrons, can only occupy distinct quantum states individually, while bosons can collectively occupy the same state simultaneously.

In the context of metals, electrons, being fermions, are the carriers of electricity. However, under specific conditions, electrons pair up to create bosonic entities. Superconductivity manifests when these electron pairs, now bosons, adopt the lowest attainable energy state. Within this state, they function as a cohesive “charge soup,” facilitating unhindered motion, resulting in zero electrical resistance — a characteristic of superconductivity.

The query arises: How do electrons form these pairs? Despite their mutual repulsion due to identical charges, they manage to pair up through a phenomenon elucidated by the BCS theory. At extremely low temperatures, an attractive force emerges between two electrons. This attraction arises due to the Coulomb interaction between an electron and the crystal lattice. When an electron traverses the lattice, it induces a marginal augmentation in positive charges around it, consequently drawing in positive ions. This augmented positive charge subsequently attracts another electron.

The underlying mechanism incorporates the metal’s atomic structure. The atoms, organized in a regular lattice pattern, are positively charged due to electron loss — these liberated electrons form the pairs. As an electron traverses an atom, the attractive force causes slight atom movement towards the electron. Given the disparity in size and mass, electrons move nimbly, whereas atoms move sluggishly, necessitating time for them to revert to their original positions in the lattice. Consequently, the electron leaves a residual disturbance — an atomic ripple — along its path. Another electron, situated some distance from the first, experiences this ripple’s effect. Attracted by the positively charged atoms, the second electron gravitates towards the ripple, fostering an indirect attraction to the first electron. This interplay engenders their joint motion as a pair.

Furthermore, superconducting materials exhibit the Meissner effect at low temperatures. The Meissner effect is a fundamental phenomenon in superconductivity where a material, upon entering its superconducting state, expels virtually all magnetic fields from its interior. This expulsion of magnetic flux is accompanied by the appearance of perfect diamagnetism, meaning that the material itself develops an opposing magnetic field to counteract any external magnetic field applied to it. As a result, the magnetic field lines are repelled from the interior of the superconductor, leading to the phenomenon of magnetic levitation when the material is placed near a magnetic source.

The Meissner effect was first discovered by physicists Walther Meissner and Robert Ochsenfeld in 1933. It is a consequence of the superconducting state’s unique properties, where electrons form pairs and move without resistance. These paired electrons, known as Cooper pairs, can collectively respond to the presence of a magnetic field by generating currents that generate counteracting magnetic fields. This behavior effectively repels the external magnetic field and causes it to be excluded from the bulk of the superconducting material.

The Meissner effect has significant practical implications and applications. It is the basis for technologies like magnetic levitation (maglev) trains, where superconducting materials allow trains to float above the tracks using the repulsive force generated by the Meissner effect. Additionally, it is a crucial property for applications in fields such as high-performance electromagnets used in medical imaging (MRI) and particle accelerators, as well as in various experimental and research contexts.

The Meissner effect is a remarkable property of superconductors, where they expel magnetic fields from their interiors and exhibit perfect diamagnetism, resulting in fascinating phenomena like magnetic levitation and various technological applications.

It’s also important to understand Phonons which are quantized units of vibrational energy that describe the collective motion of atoms in a crystalline lattice structure. They are fundamental to understanding the behavior of solids, particularly in the context of thermal and mechanical properties. Phonons play a crucial role in various phenomena, including heat conduction, thermal expansion, and the propagation of sound through solids.

In a solid material, atoms are not static; they vibrate around their equilibrium positions due to thermal energy. Phonons represent these vibrations as quantized packets of energy, somewhat similar to how photons represent packets of light energy. The concept of phonons helps explain how thermal energy travels through solids, affecting their macroscopic properties.

Phonons have different modes of vibration, often classified as acoustic and optical modes. Acoustic phonons involve collective oscillations of atoms in a way that preserves the overall lattice structure, giving rise to sound waves in the material. Optical phonons, on the other hand, involve vibrations that disrupt the symmetry of the lattice and are associated with the absorption or emission of light or infrared radiation.

Phonons are essential theoretical constructs that help us understand the behavior of atoms in a crystalline lattice. They play a crucial role in explaining thermal and mechanical properties of solids and are fundamental to the study of materials’ behavior under various conditions.

This phenomenon involves the lattice’s phonons — ripples in atomic configuration that enable sound propagation in solids. These phonons function as mediators, where the first electron emits a phonon that the second electron absorbs, effectively amalgamating them. The effectiveness of this “phonon glue” increases as the material cools due to the reduction in chaotic temperature phonons. This controlled environment ensures that only phonons from other electrons influence the pairing process, enabling the cohesive behavior of the electron pairs.

In essence, superconductors harness the intricate interplay of particle behavior, electron pairing, and lattice interactions to achieve their exceptional conductivity characteristics.

Conclusion

After studying the wonderful work of Heike Kamerlingh Onnes along with the mechanisms behind superconductivity, we can conclude:

Superconductors and Electron Pairs

Superconductors are special materials that can conduct electricity without any resistance. This happens because electrons, which are tiny particles that carry electric current, team up in pairs. Normally, electrons don’t like to be close to each other because they have the same charge and repel each other. But in superconductors, something interesting happens. At very cold temperatures, there is a force that makes electrons attract each other.

Imagine electrons moving through a crowd of atoms in a metal. When an electron moves by, it slightly shifts the positive charges of the atoms, making them move a bit too. This movement creates a little ripple, like a tiny wave, in the crowd of atoms. Another electron nearby feels this ripple and is drawn towards it. This ripple helps bring the two electrons together, and they become a pair.

Meissner Effect and Magnetic Levitation

Superconductors also do something cool when it gets really cold. They kick out almost all magnetic fields from inside them. This is called the Meissner effect. It’s like a magic shield that makes the inside of the superconductor a no-magnetic-zone. This effect makes superconductors repel from magnets, so if you put a superconductor near a magnet, it floats!

This floating effect is used in technologies like fast trains that glide above tracks (maglev trains) and powerful machines like MRI scanners in hospitals.

Phonons and Vibrations

Think of atoms in a solid material as tiny balls held in place by springs. When you heat up the material, the atoms start to jiggle around because of the heat energy. These jiggles are like vibrations or movements of the atoms. We call these vibrations “phonons.”

Phonons have different types: some make the atoms vibrate in a way that preserves the material’s shape, like sound waves in the air. Others mess up the arrangement of the atoms a bit. The first type of phonons helps electrons work together in pairs.

Putting It All Together

Superconductors are amazing materials that allow electricity to flow without any resistance. They do this by making electrons work together in pairs, even though electrons usually repel each other. This pairing happens because of special forces caused by the way electrons move through the atoms in the material. Superconductors also push away magnetic fields, making them float above magnets, which is super cool! The way atoms vibrate in the material helps electrons join forces, like teamwork, and work as pairs.

So, in simple terms, superconductors are like teamwork champions among particles, and they use clever tricks to conduct electricity perfectly and even float on magnets!

Heike Kamerlingh Onnes’ groundbreaking experiments in the liquefaction of helium and the discovery of superconductivity have forever altered the landscape of physics. His unwavering curiosity, innovative methodologies, and dedication to pushing the boundaries of knowledge have left an enduring legacy. By exploring and unraveling the mysteries of matter at extreme low temperatures, Kamerlingh Onnes not only transformed our understanding of fundamental physics but also paved the way for technological advancements that continue to shape our world today.

References:

Wikipedia contributors. Heike Kamerlingh Onnes. Wikipedia. Available at: https://en.wikipedia.org/wiki/Heike_Kamerlingh_Onnes. Accessed on August 17, 2023.

NobelPrize.org. Heike Kamerlingh Onnes — Facts. Nobel Prize. Available at: https://www.nobelprize.org/prizes/physics/1913/onnes/facts/. Accessed on August 17, 2023.

Pleffken Hosti, Brunno. Superconductivity Explained: How Heike Kamerlingh Onnes Revolutionized Physics. Espaço & Tempo. Available at: https://www.espacotempo.com.br/o-que-e-supercondutividade/. Accessed on August 17, 2023.

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