Material Matters: HDPE
High-density polyethylene (HDPE) is so ubiquitous in our world that it hardly needs introduction. Chances are you have something made of this versatile plastic nearby, whether it’s a drink bottle, mailing envelope, or grocery bag. HDPE is a synthetic polymer made from ethylene. The word polymer comes from the Greek language and literally means “many parts.”
Polymers are made up of long chains of molecules and are abundant in nature (such as plant cellulose), but synthetic polymers are made up of much longer chains than natural ones, making them stronger, lighter, and more flexible. The low degree of branching in HDPE’s molecular structure means it can withstand heavier loads. Known for its high strength-to-density ratio, HDPE can easily be machined to produce strong, lightweight parts.
History
In 1869, a firm in New York offered $10,000 to anyone who could make a substitute for ivory. John Wesley Hyatt treated cellulose from cotton fiber with camphor, and the first synthetic polymer was born. Synthetic polymer plastics were touted as the abundant and environmentally safe substitute for natural materials like wood, horn, and shells.
Shortly after, in 1907, the first fully synthetic plastic, Bakelite, was invented by Leo Baekeland. During World War II, plastic production ramped up to make everything from parachutes to body armor and aircraft windows. As the war came to an end, in the late 1940s, demand for oil tanked, and the Phillips Petroleum Company tasked their researchers J. Paul Hogan and Robert L. Banks with finding uses for propylene and ethylene, byproducts of the petroleum refining process.
In studying catalysts and how gasses could be converted into gasoline components, Hogan and Banks discovered a new polymer named crystalline polypropylene. The method they developed dramatically reduced the extreme pressure previously required to make polyethylene, and they were able to produce HDPE, which was stronger than anything comparable on the market at the time. Phillips immediately recognized the game-changing potential of HDPE and were in commercial-scale production in less than six years. They first introduced HDPE in 1954 under the brand name Marlex.
Properties
- Versatile
- Durable
- Nontoxic
- Economical
- Recyclable
- High tensile strength
- High strength-to-density ratio
- FDA-compliant for food storage
- Resistant to chemicals, UV, heat, and moisture
- Withstands loads without breaking or cracking
- Harder than other plastics and can resist higher pressures
- Carbon footprint of production is 5 times lower than aluminum
Specifications
- Density: 0.94 g/cm3
- Shore hardness: 60–70
- Tensile strength: 23.0–29.5 MPa
- Melting point: 267.4°F/130.8°C
- Specific heat capacity: 1330 to 2400 J/kg-K
- Electrical resistivity: 16–18 ohm-cm
Uses
Naturally, when a material is this versatile, durable, and economical, it’s bound to have a wide range of uses. Hogan and Banks’ discovery was even designated as a National Historic Chemical Landmark in 1999 by the American Chemical Society because of its importance and prevalence in our daily lives. The list here is by no means exhaustive but gives you an idea of how varied the uses of HDPE are, broken into categories.
Household
- Plastic bottles (e.g., detergent, milk, and shampoo)
- Grocery bags
- Mailing envelopes
- Stackable outdoor chairs
- Crates
- Toys
- Food containers
- Rope
Construction & Industrial
- Tyvek housewrap
- Plastic lumber
- Geothermal heat transfer piping systems
- Corrosion-resistant pipes
- Chemical drums
- Water infrastructure pipes
- Conduit protector for electrical and communications cables
- Geotextiles for erosion
Outdoor equipment
- Boats
- Playground equipment
- Basketball backboards
- Snowboard park boxes and rails
Other
- Medical devices
- Fuel tanks
- 3D printer filament
- Auto parts
- Syringes
CNC Spotlight
Best bits: In general, larger, single-flute 1/4”, 1/8", and 1/16" end mills are better for HDPE because they cut through material fast and create chips that can handle heat dissipation. For 3D shapes, a 1/4”, 1/8", or 1/16" ball end mill produces the smoothest contours.
Hot tips: Keep a set of end mills specifically for HDPE and other plastics, and never use them to cut metal. For example, we like to use Harvey Tool’s plastic cutters or Datron’s single-flute end mills when doing roughing operations with this engineering plastic. This helps you better manage heat, avoid chip welding, and program high-speed speeds and feeds recipes. On the flip side, for finishing passes we like to use tooling with multiple flutes like the Harvey Tool 1/8” 3-flute flat end mill to get better quality finishes. When using end mills with multiple flutes though, you’ll want to pay close attention to the feed per tooth, so you can rest assured the chips are so small they melt and stick to the tool.
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